燃料电池端板设计和生产验证实践:由接触电阻判和传质阻抗确定端板变形量、厚度优化[设计因素其十二]
Design and manufacturing of end plates of a5 kW PEM fuel cell
S.Asghari
M.H.Shahsamandi
M.R.Ashraf Khorasani
Abstract
End plate is one of the main components ofthe proton exchange membrane (PEM) fuel cells. The major role of the end plateis providing uniform pressuredistribution between various components of the fuel cell (bipolar plates, etc.)and consequently reducing contact resistance between them. In this study aprocedure for design of end plate has been developed. At first a suitablematerial was selected using various criteria. Then a finite element (FE)analysis was accomplished to analyze endplate deflections and get its optimized thickness. After fabricating theend plates, a single cell was assembled and electrochemical impedancespectroscopy (EIS) tests were carried out to ensure their good operation. A 5kW fuel cell assembled with these end plates was tested at different operatingconditions. The test results show an appropriate assembly pressure distributioninside the stack which indicates good performance of the designed end plates.
这篇文章和燃料电池电堆活性区接触应力分布的影响因素:端板厚度、端板材料、密封模型、密封件硬度、电池节数、电池位置(设计因素其二)有关联。前者计算变形,后者计算应力。
端板变形多大是允许的?
这篇文章如果结合压敏纸的数据就更加完美了。
Fig. 1 End plate roles: a) providing passages for reactant gases and coolant fluid, b) Providing uniform contact pressure distribution in the stack.
Fig. 2 e Effect of clamping pressure on the fuel cell performance.
Fig. 3 e Inserted Teflon parts into the end plate to act as the inlet and outlet passages.
Fig. 4 e Components of the geometrical model.
Fig. 5 e Load-deflection diagram of the disc spring stack used in the PEM fuel cell stack.
Fig. 6 e Contour plot of end plate deformation along direction 3.
Fig. 7 e Effect of end plate thickness on the maximum principal stress in bipolar plate.
Fig. 8 e Effect of end plate thickness on the maximum end plate displacement.
Fig. 9 e Effect of end plate thickness on the maximum bipolar plate displacement.
Fig. 10 e Impedance plots of the single cell assembled with different clamping torques but under the same operational conditions: current density: 0.18 AcmL2; stoichiometry: 1.5/2.0 for H2/air; RH: 90%; cell temperature: 70 C; back pressure: 5 psig.
Fig. 11 e Dependence of the high frequency resistance (HFR) with the clamping torque under operating conditions: current density: 0.18 A cmL2; stoichiometry: 1.5/2.0 for H2/air; RH: 90%; cell temperature: 70 C; back pressure: 5 psig.
Fig. 13 e Polarization curves of individual cells of the 5 kW stack; Powere current curve of the 5 kW stack.
Conclusion
In this study a FE model was developed to investigate the effect of end plate thickness on the deflection of bipolar plate and end plate after applying the clamping pressure.
Considering the FE results, the optimum thickness was chosen to be 35 mm. A single cell which assembled by these end plates was tested by EIS test method at different torques.
It was determined that the ohmic resistance at 25 Nm is approximately as equal as the value recommended by the MEA manufacturer. Regarding the EIS test results, the end plates were used to assemble a 5 kW PEMFC stack. Analyzing the results of the leakage test and also voltage-current diagrams of this stack determined the good performance of the end plates in producing adequate and uniform clamping pressure in the individual cells of the stack and also obtaining the desired nominal power.
关于密封测试方案与后续根据密封状态采取的措施:
Applying neutral gas with 1.5 barg pressure to all gases and cooling fluid compartments simultaneously and seeking any leakage to ambient.
Applying neutral gas with 1.5 barg pressure to cooling fluid compartment and investigating any leakage to ambient or H2 and air compartments.
Applying neutral gas with 500 mbarg pressure to each of H2 and air compartments individually and investigating any leakage to another compartment.
If the leakage is less than 20 ml/min, then anything is Ok.
If the leakage is between 20 ml/min up to 100 ml/min, then the stack could work but leakage source should be found otherwise the power output of the stack will be decreased over time.
If the leakage is more than 100 ml/min then the stack should be disassembled for finding source of leakage.
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